Ni<sub>3</sub>Se<sub>2</sub>/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究

徐登基; 李欣冉; 田地; 汪辉; 屈治国

doi:10.16152/j.cnki.xdxbzr.2026-01-006

您当前的位置：

首页 >

文章列表页 >

Ni₃Se₂/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究

能源资源的绿色低碳转化与高效利用 | 更新时间：2026-02-24

- Ni₃Se₂/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究
- Bifunctional electrocatalyst based on Ni₃Se₂/NiSe@NF: Fabrication and performance in electrocatalytic hydrogen and oxygen evolution
- 西北大学学报（自然科学版） 2026年56卷第1期页码：57-67
- 作者机构：
  
  西安交通大学　热流科学与工程教育部重点实验室，能源与动力工程学院，陕西　西安　710049
- 作者简介：
  
  徐登基，男，博士研究生，从事海水电解制氢催化剂的制备与应用研究，djxu0407@stu.xjtu.edu.cn。
  屈治国，男，教授，博士生导师，从事高效传热与节能技术、电化学储能与氢燃料电池、太阳能高效利用，电子器件热管理研究，zgqu@mail.xjtu.edu.cn。
- 基金信息：
  
  国家重点研发计划项目(2023YFB4004603);国家自然科学基金(52025065)
- DOI：10.16152/j.cnki.xdxbzr.2026-01-006
  中图分类号： TQ426
- 收稿：2025-06-12，
  
  修回：2025-07-10，
  
  纸质出版：2026-02-25
- 稿件说明：
移动端阅览
徐登基, 李欣冉, 田地, 等. Ni₃Se₂/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究[J]. 西北大学学报（自然科学版）, 2026,56(1):57-67.

XU Dengji, LI Xinran, TIAN Di, et al. Bifunctional electrocatalyst based on Ni₃Se₂/NiSe@NF: Fabrication and performance in electrocatalytic hydrogen and oxygen evolution[J]. Journal of Northwest University (Natural Science Edition), 2026, 56(1): 57-67.
徐登基, 李欣冉, 田地, 等. Ni₃Se₂/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究[J]. 西北大学学报（自然科学版）, 2026,56(1):57-67. DOI： 10.16152/j.cnki.xdxbzr.2026-01-006.

XU Dengji, LI Xinran, TIAN Di, et al. Bifunctional electrocatalyst based on Ni₃Se₂/NiSe@NF: Fabrication and performance in electrocatalytic hydrogen and oxygen evolution[J]. Journal of Northwest University (Natural Science Edition), 2026, 56(1): 57-67. DOI： 10.16152/j.cnki.xdxbzr.2026-01-006.

摘要

为解决传统电催化剂成本高、电解效率低等问题，推动规模化绿氢制备技术的发展，本研究通过结构设计与合成工艺优化，成功构建了基于过渡金属镍的硒化物异质结催化剂。采用两步水热法在泡沫镍（NF）基底上制备了具有界面结构的Ni

/NiSe@NF异质结双功能电催化剂。与单一物相催化剂（Ni

@NF和NiSe@NF）相比，Ni

/NiSe@NF异质界面处发生的强电子相互作用可以有效调控活性位点的电子结构，从而显著提升其在析氢反应（HER）和析氧反应（OER）中的催化活性。在1 mol/L的KOH电解液中，Ni

/NiSe@NF在电流密度为10 mA·cm

-2

时，HER和OER过电位分别为71 mV与207 mV，并表现出优异的稳定性（持续运行500 h后活性未发生明显衰减）。此外，以Ni

/NiSe@NF同时作为阳极和阴极组装的电解槽，在10 mA·cm

-2

电流密度下仅需1.52 V的槽压即可稳定运行。研究结果为开发低成本、高稳定性的电解水催化剂提供了新思路，有助于推进绿氢制备与可再生能源系统的融合应用，对实现“双碳”目标具有积极意义。

Abstract

In order to solve the problems of high cost and low electrolytic efficiency of traditional catalysts and realize the development of large-scale green hydrogen production technology

an interfacial catalyst based on transition metal was constructed by structural design and synthesis optimization in this study. The Ni

/NiSe @NF heterojunction bifunctional electrocatalyst with interface structure was prepared on a nickel foam (NF) substrate by a two-step hydrothermal method. The strong charge transfer at the heterogeneous interface of Ni

/NiSe@NF effectively optimizes the electronic structure of Ni

/NiSe@NF compared with the single interface (Ni

@NF and NiSe@NF)

thus increasing the activities of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The prepared Ni

/NiSe@NF has an overpotential of 71 and 207 mV (10 mA·cm

-2

) at 1 mol/L KOH

respectively

and has impressive stability (no significant degradation within 500 h). In addition

when the current density is 10 mA·cm

-2

the current of the monolithic water decomposition electrolyzer with Ni

/NiSe@NF as anode and cathode can be reduced to 1.52 V. Therefore

this study provides a new idea for the development of low-cost and high-stability catalysts for water electrolysis

which is expected to accelerate the integration of green hydrogen preparation and renewable energy systems

and help realize the goal of “dual-carbon”.

关键词

Keywords

references

赵明娟 , 夏霁雯 , 苟蕾 . 以MOFs为前驱体合成NaTi 2 (PO 4 ) 3 /C及其电化学性能 [J ] . 西北大学学报(自然科学版) , 2019 , 49 ( 2 ): 289 - 294 .

ZHAO M J , XIA J W , GOU L . Synthesis and electrochemical performance of NaTi 2 (PO 4 ) 3 /C prepared by using MOFs as precursor [J ] . Journal of Northwest University (Natural Science Edition) , 2019 , 49 ( 2 ): 289 - 294 .

李壮 , 王子齐 , 张磊 . 环境和气候技术转移新生代：主体、机制和模式创新 [J ] . 西北大学学报(自然科学版) , 2021 , 51 ( 4 ): 665 - 674 .

LI Z , WANG Z Q , ZHANG L . New generation of environment and climate technology transfer: Actors, mechanism and model innovation [J ] . Journal of Northwest University (Natural Science Edition) , 2021 , 51 ( 4 ): 665 - 674 .

刘强 , 邓旭 , 王博文 , 等 . “一带一路”沿线国家能源部门气候变化减缓技术需求评估 [J ] . 西北大学学报(自然科学版) , 2021 , 51 ( 4 ): 675 - 683 .

LIU Q , DENG X , WANG B W , et al . Climate change mitigation technology needs assessment for energy sector in countries along the Belt and Road [J ] . Journal of Northwest University (Natural Science Edition) , 2021 , 51 ( 4 ): 675 - 683 .

顾鑫 , 尚鑫超 , 王明清 , 等 . 超分子聚合物衍生的新型Nb(PO 4 )O的制备及其在钠离子电池中的应用 [J ] . 西北大学学报(自然科学版) , 2024 , 54 ( 2 ): 220 - 229 .

GU X , SHANG X C , WANG M Q , et al . Preparation of new Nb(PO 4 )O derived from supramolecular polymer and its application in sodium ion batteries [J ] . Journal of Northwest University (Natural Science Edition) , 2024 , 54 ( 2 ): 220 - 229 .

石涵笑 , 韦安磊 , 朱娅绮 , 等 . 榆林市工业二氧化碳与大气污染物排放控制协同效应研究 [J ] . 西北大学学报(自然科学版) , 2024 , 54 ( 3 ): 424 - 433 .

SHI H X , WEI A L , ZHU Y Q , et al . Study on the synergistic effect of industrial carbon dioxide and atmospheric pollutant emission control in Yulin City [J ] . Journal of Northwest University (Natural Science Edition) , 2024 , 54 ( 3 ): 424 - 433 .

YU Z Y , DUAN Y , FENG X Y , et al . Clean and affordable hydrogen fuel from alkaline water splitting: Past, recent progress, and future prospects [J ] . Advanced Materials , 2021 33 : 2007100 .

高敏 , 王蒙 , 肖霞 , 等 . TiO 2 /g-C 3 N 4 复合物的光催化性能测试及机理研究 [J ] . 西北大学学报(自然科学版) , 2018 , 48 ( 1 ): 71 - 77 .

GAO M , WANG M , XIAO X , et al . TiO 2 /g-C 3 N 4 composites performed ophotocatalysis and the deduction of enhanced mechanism [J ] . Journal of Northwest University (Natural Science Edition) , 2018 , 48 ( 1 ): 71 - 77 .

WANG J , LIANG C , MA X , et al . Dynamically adaptive bubbling for upgrading oxygen evolution reaction using lamellar fern-like alloy aerogel self-standing electrodes [J ] . Advanced Materials , 2023 , 36 : 2307925 .

高林 , 郑雅文 , 杨东泰 , 等 . 构建碳中和电力系统——碳中和公式 [J ] . 科学通报 , 2021 , 66 ( 31 ): 3932 - 3936 .

GAO L , ZHENG Y W , YANG D T , et al . Criterial equation of carbon neutrality for power systems [J ] . Chinese Science Bulletin , 2021 , 66 ( 31 ): 3932 - 3936 .

WANG X , CHAI L , DING J , et al . Chemical and morphological transformation of MOF-derived bimetallic phosphide for efficient oxygen evolution [J ] . Nano Energy , 2019 , 62 : 745 - 753 .

RAN Z , SHU C , HOU Z , et al . Modulating electronic structure of honeycomb-like Ni 2 P/Ni 12 P 5 hetero structure with phosphorus vacancies for highly efficient lithium-oxygen batteries [J ] . Chemical Engineering Journal , 2021 , 413 : 127404 .

SUN L , LUO Q , DAI Z , et al . Material libraries for electrocatalytic overall water splitting [J ] . Coordination Chemistry Reviews , 2021 , 444 : 214049 .

ZHANG Z , LEI Y , HUANG W , et al . Recent progress in carbonbased materials boosting electrochemical water splitting [J ] . Chinese Chemical Letters , 2022 , 33 : 3623 - 3631 .

LI G , HAN G , WANG L , et al . Dual hydrogen production from electrocatalytic water reduction coupled with formaldehyde oxidation via a copper-silver electrocatalyst [J ] . Nature Communications , 2023 , 14 ( 1 ), 525 .

WANG T , LIAO X , ZHANG T , et al . CoP aerogels assisted by selenite etching as high activity electrocatalysts for water splitting [J ] . Composites Part B: Engineering , 2023 , 254 : 110601 .

POONIA K , SINGH P , SINGH A , et al . Photoelectrocatalytic systems for simultaneous energy recovery and wastewater treatment: A review [J ] . Environmental Chemistry Letters , 2022 , 21 : 265 - 283 .

TAN P , GAO R , ZHANG Y , et al . Electrostatically directed assembly of two-dimensional ultrathin Co 2 Ni-MOF/Ti 3 C 2 T x nanosheets for electrocatalytic oxygen evolution [J ] . Journal of Colloid and Interface Science , 2023 , 630 : 363 - 371 .

TANG X , LI N , PANG H . Metalorganic frameworks-derived metal phosphides for electrochemistry application [J ] . Green Energy & Environment , 2022 , 7 : 636 - 661 .

HU H , ZHANG Z , ZHANG Y , et al . An ultra-low Pt metal nitride electrocatalyst for sustainable seawater hydrogen production [J ] . Energy & Environmental Science , 2023 16 : 4584 - 4592 .

GUO M , DENG R , WANG C , et al . Recent progress of advanced manganese oxide-based materials for acidic oxygen evolution reaction: Fundamentals, performance optimization, and prospects [J ] . Journal of Energy Chemistry , 2023 , 78 : 537 - 553 .

ZHOU X , HU J , AJMAL S , et al . In situ grown high-valence Mo-doped NiCo Prussian blue analogue for enhanced urea electrooxidation [J ] . Chemical Communications , 2023 , 59 : 12152 - 12155 .

GAO J , MA H , ZHANG L , et al . Interface engineering of Ni 3 Se 2 @FeOOH heterostructure nanoforests for highly-efficient overall water splitting [J ] . Journal of Alloys and Compounds , 2022 , 893 : 162244 .

DENG R , YAO H , WANG Y , et al . Interface effect of Fe doped NiSe/Ni 3 Se heterojunction as highly efficient electrocatalysts for overall water splitting [J ] . Chemical Engineering Journal , 2024 , 488 : 150996 .

CHEN T Y , VEDHANARAYANAN B , LIN S Y , et al . Electrodeposited NiSe on a forest of carbon nanotubes as a free-standing electrode for hybrid supercapacitors and overall water splitting [J ] . Journal of Colloid and Interface Science , 2020 , 574 : 300 - 311 .

PENG X , YAN Y , XIONG S , et al . Se-NiSe 2 hybrid nanosheet arrays with self-regulated elemental Se for efficient alkaline water splitting [J ] . Journal of Materials Science & Technology , 2022 , 118 : 136 - 143 .

ISLAM M , TRAN D T , NGUYEN T H , et al . Efficient synergism of NiO-NiSe 2 nanosheet-based heterostructu res shelled titanium nitride array for robust overall water splitting [J ] . Journal of Colloid and Interface Science , 2022 , 612 : 121 - 131 .

ZHOU H , ZHANG D , DONG W , et al . Stainless steel mesh-based CoSe/Ni 3 Se 4 heterostructure for efficient electrocatalytic overall water splitting [J ] . International Journal of Hydrogen Energy , 2023 , 48 : 14554 - 14564 .

ZHANG F , PEI Y , GE Y , et al . Controlled Synthesis of Eutectic NiSe/Ni 3 Se 2 Self-Supported on Ni Foam: An excellent bifunctional electrocatalyst for overall water splitting [J ] . Advanced Materials Interfaces , 2018 , 5 : 1701507 .

ZHANG C , LI T , WEI Q , et al . Fe-doped NiSe 2 nanoparticles as efficient and stable electrocatalysts for oxygen evolution reaction [J ] . Chemical Physics Letters , 2022 , 808 : 140126 .

ZHAO J , YANG L , LI H , et al . Ni 3 Se 2 nanosheets in-situ grown on 3D NiSe nanowire arrays with enhanced electrochemical perform ances for supercapacitor and efficient oxygen evolution [J ] . Materials Characterization , 2021 , 172 : 110819 .

ZARE A , BAYAT A , SAIEVAR-IRANIZAD E , et al . One step preparation of Fe doped CoSe 2 supported on nickel foam by facile electrodeposition method as a highly efficient oxygen evolution reaction electrocatalyst [J ] . Journal of Electroanalytical Chemistry , 2020 , 878 : 114595 .

VIGNESHRAAJ A S , RAMESH S K , KIM J , et al . Phase-dependent electronic structure modulation of nickel selenides by Fe doping for enhanced bifunctional oxygen electrocatalysis [J ] . Nanoscale , 2025 , 17 : 4556 - 4569 .

GUO K , JIA J , WANG H , et al . Structural tuning and reconstruction of CeO 2 -coupled nickel selenides for robust water oxidation [J ] . Chinese Chemical Letters , 2025 : 110888 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据

Ni3Se2/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究

Bifunctional electrocatalyst based on Ni3Se2/NiSe@NF: Fabrication and performance in electrocatalytic hydrogen and oxygen evolution

DOI：10.16152/j.cnki.xdxbzr.2026-01-006

摘要

Abstract

关键词

Keywords

references

Ni₃Se₂/NiSe@NF双功能催化剂制备及其电催化产氢产氧性能研究

Bifunctional electrocatalyst based on Ni₃Se₂/NiSe@NF: Fabrication and performance in electrocatalytic hydrogen and oxygen evolution