磷灰石结构碳酸盐团簇同位素测温法研究进展

陈延龙; 席海斌; 王珮瑶

doi:10.16152/j.cnki.xdxbzr.2025-03-014

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磷灰石结构碳酸盐团簇同位素测温法研究进展

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- 磷灰石结构碳酸盐团簇同位素测温法研究进展
- Research progress in clumped isotope thermometry of apatite structural carbonate
- 西北大学学报（自然科学版） 2025年55卷第3期页码：668-678
- 作者机构：
  
  西北大学　地质学系/大陆演化与早期生命全国重点实验室，陕西省早期生命与环境重点实验室，陕西　西安　 710069
- 作者简介：
  
  [ "陈延龙，西北大学副教授，主要从事早古生代以及古生代与中生代之交磷灰石质化石及生物与古环境协同演化的研究。主持国家自然科学面上及青年基金、国家重点研发计划二级子课题等多项科研项目。现任中国古生物学会新技术新方法专业委员会委员、陕西省古生物学会副秘书长。主持2023年国家级一流本科课程1项（虚拟仿真实验教学一流本科课程），该课程入选虚拟仿真实验教学创新联盟2022年度实验教学应用示范课程及陕西省一流本科课程。曾获2023年第十四届陕西青年科技奖等。在Science、Geology、Earth-Science Reivews等国内外学术期刊累计发表学术论文30余篇，成果曾入选2021年“全国地质古生物科普十大进展”。" ]
- 基金信息：
  
  国家重点研发计划(2023YFF0803601);国家自然科学基金(42172013;41720104002;W2441016);地球多圈层相互作用的油气富集理论研究项目(THEMSIE04010106)
- DOI：10.16152/j.cnki.xdxbzr.2025-03-014
  中图分类号： P597
- 收稿日期：2025-05-12，
  
  纸质出版日期：2025-06-25
- 稿件说明：
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陈延龙, 席海斌, 王珮瑶. 磷灰石结构碳酸盐团簇同位素测温法研究进展[J]. 西北大学学报（自然科学版）, 2025,55(3):668-678.

CHEN Yanlong, XI Haibin, WANG Peiyao. Research progress in clumped isotope thermometry of apatite structural carbonate[J]. Journal of northwest university (natural science edition), 2025, 55(3): 668-678.
陈延龙, 席海斌, 王珮瑶. 磷灰石结构碳酸盐团簇同位素测温法研究进展[J]. 西北大学学报（自然科学版）, 2025,55(3):668-678. DOI： 10.16152/j.cnki.xdxbzr.2025-03-014.

CHEN Yanlong, XI Haibin, WANG Peiyao. Research progress in clumped isotope thermometry of apatite structural carbonate[J]. Journal of northwest university (natural science edition), 2025, 55(3): 668-678. DOI： 10.16152/j.cnki.xdxbzr.2025-03-014.

摘要

古温度重建对于理解地球气候变化及生命演化意义重大，传统基于δ

O的测温法因依赖古海水氧同位素组成（δ

）而具有不确定性。近20年发展的碳酸盐团簇同位素（Δ

）测温法因无需已知δ

，成为研究热点，但是常用材料碳酸盐极易造受成岩作用改造而丢失原始温度信息。而磷灰石作为一种含碳酸盐结构且具有较强的抵御成岩作用改造能力的载体，能够较好的保存原始同位素信息，因而成为深时古气候研究的理想材料。该文对磷灰石结构碳酸盐的团簇同位素研究进行了系统回顾与综述，探讨了磷灰石结构碳酸盐的Δ

与温度的校准关系式存在问题及可能的动力学效应。另外，有机质含量、动力学效应及成岩作用（重结晶、固态重排）均可能导致测温偏差。未来需完善校准关系，并结合多同位素及微量元素分析提升数据可靠性。随着研究深入，磷灰石结构碳酸盐团簇同位素分析技术有望为深时古气候等方向的研究带来突破。

Abstract

Reconstructing paleo-temperatures is of great significance for understanding the Earth’s climate changes and the evolution of life. Traditional thermometry based on δ

O has uncertainties due to its reliance on the oxygen isotope composition of seawater (δ

). Carbonate clumped isotope (Δ

) thermometry

which was developed over the past 20 years

has become a research hotspot as it does not require prior knowledge of δ

. However

carbonates

which are the most commonly used material for Δ

thermometry

are highly susceptible to diagenetic alteration

sometimes leading to the loss of original temperature information. Therefore

apatite

which contains structurally bound carbonate and exhibits strong resistance to diagenetic modification

has been an ideal material for studying deep-time paleoclimates. This paper reviews the research on apatite clumped isotopes

discussing the issues in the

calibration relationships between apatite Δ

and temperature

as well as potential kinetic effects. Additionally

factors such as organic matter content

kinetic effects

and diagenetic processes (recrystallization and solid-state reordering effects) may all introduce biases in thermometric results. In the future

it will be necessary to refine the calibration relationships

integrate multi-isotope and trace element analyses to enhance data reliability. With further research

apatite clumped isotope technology is expected to bring breakthroughs to studies in deep-time paleoclimatology and related fields.

关键词

Keywords

references

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