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1.中国石油天然气股份有限公司 西南油气田公司,四川 成都 610051
2.西北大学 化工学院,陕西 西安 710127
兰云霞,女,高级工程师,从事天然气采输研究,lanyx@petrochina.com.cn。
朱亮亮,博士,副教授,从事二氧化碳捕集与资源化利用研究,zhu.liangliang@nwu.edu.cn。
收稿:2025-01-10,
纸质出版:2025-10-25
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LAN Yunxia, ZHENG Shiqiang, XIE Yang, et al. The formation of activated carbon-based moisture-swing adsorbents and their CO2 direct air capture performance[J]. Journal of northwest university (natural science edition), 2025, 55(5): 970-978.
兰云霞, 郑世强, 谢洋, 等. 活性炭基变湿吸附剂的成型及其CO2直接空气捕集性能研究[J]. 西北大学学报(自然科学版), 2025,55(5):970-978. DOI: 10.16152/j.cnki.xdxbzr.2025-05-003.
LAN Yunxia, ZHENG Shiqiang, XIE Yang, et al. The formation of activated carbon-based moisture-swing adsorbents and their CO2 direct air capture performance[J]. Journal of northwest university (natural science edition), 2025, 55(5): 970-978. DOI: 10.16152/j.cnki.xdxbzr.2025-05-003.
CO
2
直接空气捕集(DAC)变湿吸附剂的研究多数是固体粉末状材料,不利于大规模工程应用。通过将活性炭(AC)与黏合剂甲基纤维素和膨润土复合,并进一步负载K
2
CO
3
,制备了用于CO
2
直接空气捕集的K
2
CO
3
/AC成型吸附剂,并通过表征测试及C
O
2
吸附性能测试,评估了其实用性能。实验结果显示,成型后的吸附剂具有良好的抗压强度和CO
2
吸附性能。随着成型吸附剂中AC含量的增加,其CO
2
直接空气捕集吸附量呈上升趋势。AC质量分数为60%的K
2
CO
3
/AC-60成型吸附剂具有最优的抗压强度,其吸附量可达到0.319 mmol/g。研究结果为粉末状变湿吸附剂的成型和工业化应用提供了科学依据,对于开发实用化的DAC吸附剂具有重要意义。
Currently
most research on moisture-swing adsorbents for CO
2
direct air capture (DAC) technology focuses on solid powder materials
which hinder large-scale engineering applications. By compositing activated carbon (AC) with binders such as methylcellulose and bentonite
and further loaded with K
2
CO
3
a K
2
CO
3
/AC shaped adsorbent for direct air capture of CO
2
was prepared. Its practical performance was evaluated through characterization tests and CO
2
adsorption performance tests. Experimental results indicate that the shaped adsorbent exhibits good compressive strength and CO
2
adsorption performance under DAC circumstances. As the AC content in the shaped adsorbent increases
the adsorption capacity for DAC shows an upward trend. The K
2
CO
3
/AC-60 shaped adsorbent with an AC mass fraction of 60% has the optimal compressive strength and its adsorption capacity can reach 0.319 mmol/g. This study provides a scientific basis for the formation and industrial application of powder moisture-swing adsorbents
and holds great significance for the development of practical DAC adsorbents.
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